Chapter

Crystalline Structure of Fullerene Solids 171

7.1. Crystalline Cw 171

7.1.1. Ambient Structure 173

7.1.2. Group Theory for Crystalline Phases 175

7.1.3. Low-Temperature Phases 184

7.1.4. Merohedral Disorder 193

7.1.5. Model for Phase Transitions in C60 194

7.2. Crystalline C70 and Higher-Mass Fullerenes 197

7.3. Effect of Pressure on Crystal Structure 203

7.4. Effect of Temperature on Crystal Structure 208

7.5. Polymerized Fullerenes 209

7.5.1. Photopolymerization of C60 209

7.5.2. Electron Beam-Induced Polymerization of C60 212

7.5.3. Pressure-Induced Polymerization of C60 213

7.5.4. Plasma-Induced Polymerization of C60 214

7.5.5. Photopolymerization of C70 Films 215

References 217

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