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porphyrin 139 potential of zero charge 94

Au(lll) 94; 96 potential programs 279 pre-passive layer 205; 206 protoporphyrin DC 42 Pt columnar-structured 66 Pt cluster on HOPG 79; 83 Pt(lll)

iodine adlayer 137; 138; 139; 140; 142; 143;

144; 146

modification by ruthenium 74; 75; 76 nanometer-sized particles 74; 75; 76 Ru-modified 74; 75; 76 underpotential deposition of Ag 137; 138;

139; 140; 142; 143; 144; 146 underpotential deposition of Cu 143 Pt/Irtips 3; 220 pulse plating 37

STM images of copper 36 purine 107 pyramidal structures AFM images 260 pyrimidine 107 pyrolytic graphite 28 quantum dots 40 Raman spectroscopy 277 random deposition model 59; 62 random diffusion 48 rapid growth 166 reactive surfaces 166; 167 reactivity 74; 75; 80; 83; 84; 85 real surfaces 63 real-space information 74 reconstruction 160; 161; 162; 164; 166

redox films 125; 126 reductive desorption 177 RHEED 186

resonance Raman spectroscopy excitation profile 41 resonance tunneling 40 resonant tunneling modes 126 Rh(lll) RNA 107 roughness 57; 66 RU complex

STM image 129 Ru coverage 75 Ru/Pt(l 11) electrodes 75 scaling problem 80 scanning force microscopy 2, 3 scanning near-field optical microscope 110 scanning tunneling microscopy 2; 125; 126; 149; 150; 151; 152; 153; 185; 186; 187; 188; 190; 191; 192; 193; 194; 195; 196; 199; 202; 203; 204; 205; 207; 208; 209; 212; 213; 215; 225; 226; 227; 228; 229; 231; 232; 233; 234; 235; 238; 254

analytical applications 74; 75; 77; 78; 79; 80; 82; 84; 85 Au(100)-c(2 x 2)-Se 274 catalytically active monolayers 113 combination with microelectrochemistry 212 deposition of Cu 113 electrodeposition 171 ex-situ 57; 58; 61; 64; 66; 67; 68; 69 GaAs etching 248 hydroxide adlattice on Cu 113 in-situ 57; 58; 61; 64; 66; 67; 68; 69; 267 molecular adsorbates on Au and Ag 113 n-Si(lll) 244; 245; 250 strained-layer 171 superlattices 171 scanning tunneling microscopy images copper crystallites 32 figures machined 35 scattering cross-section 48 screw dislocations 16; 193 Se on Au(100) (3 x VlO) structure 273 c(2 x 2)-structure 273 p(2x2)-Se 273 Se8 rings 274

second-harmonic generation 108 second-order phase 163

selective deposition

Cu 264 self-assembling iodine-modified electrodes 139; 144 self-assembly 121; 127; 130; 131 semiconductor 13; 15; 253; 254

passivated 243 sensor technology 150 Se amorphous layer 256 SERS

time dependence 286 Shuttleworth equation 93 Si(lll)

stepped 53 silver cyanide complexes 285 single crystal 149; 152 single-electron transfer processes 40 Si anisotropic etching 242 ideally flat surfaces 246 oxide formation 242 selective oxide stripping 242 Si etching 241 Si(100) 22 Si/Ti/Ti02-x 216; 222 signal-to-noise ratio 297; 300 Si-H bonds 244 Si-O bonds 244 Si-OH surface groups 245 Si-phenyl bonds 249 space charge layer 254 spectral power density 119 spectrometer 278 SrTi03 single-crystal 24 stainless steel 1.4301/sulfuric acid AFM image 208

distance modulation spectroscopy 208

lateral force microscopy 208

local potentiodynamic polarization 200;

203; 206; 207; 208; 209; 210; 211 MnS inclusions 200; 203; 206; 207; 208;

209; 210; 211 STM image 208

tunneling barrier height 200; 203; 206; 207;

208; 209; 210; 211 stainless steel 1.4529/sulfuric acid 203; 206; 207

step curvature 179 step edge 161; 166

step edge mobility 175

step orientation 182

step polarization 5; 6; 7

step-mediated growth 182

stiffness 226; 227; 231

Stoney's equation 91

Stranski-Krastanov 17; 18; 33; 59

stress measurements 87

stress sensor schematic diagram 87; 89; 90; 94; 97 stress-voltage curve derivative 94; 97 structural characterization 75; 80; 84 structural transitions 160 structure and reactivity correlation 75; 80; 85 submicron fabrication 262 suboxide nano cluster 246 sulfamate electrolyte 216 sulfate adsorption 143 sulfate superstructure 162 sulfuration 248 superconductor 13; 15 supersaturation 14; 15 supramolecular organization 37 surface cluster distribution 277 surface defects 2; 15; 102; 103 surface diffusion 53

anisotropic 50 surface diffusion model 68 surface dynamics 27 surface energy 93; 94 surface enhanced Raman spectroscopy 108;

277; 278 surface imperfections 33 surface mean height 60 surface mobility 36 surface modification 262 surface morphology 1; 2; 3; 4; 5; 7; 8; 9; 10;

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