Scanning Probe Microscopy Studies of Molecular Redox Films


1 Introduction 125

2 Structural studies of molecular redox films 126

2.1 Covalent binding 127

2.2 Polymerization 129

2.3 Self-assembly 130

3 Electrochemical force spectroscopy 132

4 Conclusions 134

5 References 135

Summary. Scanning probe microscopy studies of electrodes chemically modified with electroactive transition metal complexes are described. Emphasis is placed on scanning tunneling microscopy and electrochemical scanning tunneling microscopy studies of their structure and dynamics of formation and on electrochemical force spectroscopy studies of their electrochemical potential dependent chemical properties.

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