Preparation And Properties Of Alkanethiol Selfassembled Monolayers

In this section, the formation of SAMs, their structure, and important variables in their preparation will be discussed. As there are many types of organosulfur molecules that self-assemble on a variety of metal surfaces (all of which can give subtle differences in SAM structure), SAM preparation procedures and so on, the discussion below will refer to long chain aliphatic alkanethiols (typically either dodecanethiol or hexadecanethiol) adsorbed onto gold surfaces unless otherwise stated.

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